Iron(iii) sulfide additionally called ferric sulfide or iron sesquisulfide is among the members that iron(3+) sulfides through IUPAC name iron(3+) trisulfide and also chemical formula Fe2S3 <1, 2>. The is a reasonably unstable synthetic black solid that decomposes and also turns into a yellow-green powder at room temperature <2>.
Iron(III) Sulfide Identification | |
CAS Number | 12063-27-3 <1> |
PubChem CID | 160957 <1> |
ChemSpider ID | 141408 <3> |
EC Number | 234-367-5 <1> |
ChEBI ID | CHEBI:75899 <2> |
InChI Key | KAEAMHPPLLJBKF-UHFFFAOYSA-N <1> |
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Iron(iii) Sulfide Formula
Composition and also Synthesis
It is created by the enhancement of cooled iron(iii) chloride solution to refrigerated salt sulfide solution, as stood for by the adhering to equation:
2FeCl3 + 3Na2S → Fe2S3 + 6NaCl
It can also be synthesized as a by-product the desulfurization of hydrogen sulfide gas that is passed through hydrated iron(iii) oxide:
Fe2O3 + 3H2S + H2O → Fe2S3 + 4H2O

Iron(iii) Sulfide
Reaction with Hydrogen Chloride
It experience a decomposition reaction when merged with hydrochloric acid <4>:
Fe2S3 + 4HCl → 2FeCl2 + 2H2S + S
Properties and Characteristics that Iron(III) Sulfide
General Properties | |
Molar Mass/Molecular Weight | 207.87 g/mol <1> |
Physical Properties | |
Color and Appearance | Turns into yellowish-green powder at room temperature <5> |
Melting Point | Decomposes |
Boiling Point | N/A <5> |
Density | 4.3 g cm-3 <5> |
State of matter at room temperature | Solid <1> |
Solubility | Moderately soluble in acids |
Solubility in Water | Very slightly dissolve in water <1> |
Use
As a source of sulfur and also iron(ii) sulfide during the decay of ferric sulfide in ~ room temperature (about 20 °C).
References
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